Product Name: Tripropylene Glycol n-Butyl Ether
Chemical Family: Glycol Ethers
Synonyms: TPNB, TPnB Ether, Propylene Glycol Ethers
CAS Number: 55934-93-5
Recommended Use: Used in cleaners, coatings, adhesives, and chemical intermediates
Supplier Info: Manufacturer and emergency contact number listed on container; keep details handy for prompt communication during emergencies or procurement
Emergency Phone Number: Listed on shipping document and label
GHS Classification: Eye Irritation: Category 2A; Skin Irritation: Category 3
Label Elements: Warning symbol; phrases: Causes serious eye irritation, may cause mild skin irritation
Signal Word: Warning
Precautionary Statements: Wear protective gloves and eye protection; wash hands after handling; avoid breathing mist or vapors; call a doctor if exposed or feeling unwell
Hazards Not Otherwise Classified: Prolonged exposure can cause headaches, dizziness, and potential harm to liver with repeated contact
Chemical Name: Tripropylene Glycol n-Butyl Ether
Concentration: 99% or greater by weight
Other Components: Trace stabilizers or impurities less than 1% total, which could vary depending on supplier and production method
CAS Number: 55934-93-5
Inhalation: Move to fresh air, seek medical attention if symptoms persist, such as difficulty breathing or persistent coughing
Skin Contact: Remove contaminated clothing and wash affected area thoroughly with soap and water, seek attention if skin continues to feel irritated
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses when present and continue rinsing, get immediate help for redness, pain, or vision changes
Ingestion: Rinse mouth, do not induce vomiting unless told by medical personnel, get help if swallowed and symptoms like nausea or abdominal discomfort persist
General Advice: Show label and this sheet to emergency responders for quick reference during first aid
Suitable Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide extinguishers
Unsuitable Media: Direct water jets can spread burning liquid
Special Hazards: Combustion can yield carbon oxides and irritant fumes; containers exposed to fire may rupture
Protective Equipment for Firefighters: Full protective gear and self-contained breathing apparatus to avoid inhaling vapors or combustion products
Fire-Fighting Instructions: Keep cool with water spray, avoid spreading runoff to drains or water sources
Personal Precautions: Wear respiratory protection, chemical goggles, gloves, and work clothing
Environmental Precautions: Prevent product from entering sewer, waterways, or soil by diking with non-combustible material
Containment Methods: Stop leak if it is safe, use inert absorbent (sand or earth) to soak up spilled liquid
Clean-up Procedures: Collect absorbed material in sealed containers for disposal, ventilate area, avoid creating mist or aerosol during cleanup
Handling: Avoid contact with skin, eyes, and clothing, do not breathe vapor or mist, use only in well-ventilated spaces, keep away from sources of ignition, wash hands after handling
Storage: Store in tightly sealed original containers away from direct sunlight and incompatible substances, in cool, dry places
Incompatible Materials: Strong oxidizers, acids, alkalis
Other Considerations: Keep container upright to prevent leakage; label all containers clearly for workplace safety
Occupational Exposure Limits: No established ACGIH or OSHA limits; employer should use good industrial hygiene controls
Engineering Controls: Provide adequate mechanical ventilation, especially in enclosed work areas
Respiratory Protection: Use NIOSH-approved mask if airborne vapors or mists are likely
Eye Protection: Chemical splash goggles
Hand Protection: Butyl rubber or nitrile gloves
Other Protective Equipment: Long sleeves, closed shoes, and face shield during possible splash risk
Appearance: Clear, colorless to slightly yellow liquid
Odor: Mild ether-like
Odor Threshold: Not determined
pH: Not applicable (neutral)
Melting Point / Freezing Point: -59°C (-74°F)
Boiling Point: 256–270°C (493–518°F)
Flash Point: 132°C (270°F) (closed cup method)
Evaporation Rate: Slower than water
Flammability: Not classified as highly flammable
Upper / Lower Flammability Limits: Not available
Vapor Pressure: <0.01 mmHg @ 20°C
Vapor Density: >1 (air = 1)
Relative Density: 0.95–0.98 (water = 1)
Solubility in Water: Moderate
Partition Coefficient (n-octanol/water): log Kow 1.5–2.2
Auto-ignition Temperature: >200°C
Decomposition Temperature: Not available
Viscosity: 8–13 cP
Explosive Properties: Not explosive
Oxidizing Properties: Not classified as an oxidizer
Chemical Stability: Stable under normal temperature and pressure
Hazardous Reactions: Can react with strong oxidizers, acids, and bases to release heat
Conditions to Avoid: High temperatures, open flames, strong sunlight
Incompatible Materials: Alkali metals, strong acids, oxidizing agents
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, and possibly irritating organic vapors on burning or decomposition
Routes of Exposure: Inhalation, eye contact, skin contact, ingestion
Acute Toxicity: Low oral and dermal toxicity; ingestion can cause gastrointestinal irritation, headache, dizziness
Chronic Effects: Repeated or prolonged exposure may affect liver and kidneys; chronic skin exposure may lead to dermatitis
Carcinogenicity: Not classified as a carcinogen under IARC, NTP, OSHA
Other Effects: Eye irritation typical at moderate concentrations; respiratory discomfort at high vapor levels
Ecotoxicity: Moderate aquatic toxicity to fish and invertebrates; spillages can disrupt water bodies
Persistence and Degradability: Readily biodegradable under aerobic conditions
Bioaccumulation Potential: Low potential as shown by low partition coefficient
Mobility in Soil: Moves through soil slowly due to moderate solubility; risk of groundwater contamination if large volumes released
Other Effects: Wastewater containing glycol ethers should be treated before release
Waste Disposal Methods: Unused product and contaminated absorbents should go to approved chemical disposal or incineration facility
Container Handling: Containers must be thoroughly emptied and triple-rinsed; recycle or dispose according to local rules
Prohibited Disposal Methods: Avoid pouring into drains, surface water or unprotected ground
Regulatory Waste Codes: Generators responsible for evaluating waste according to local and national codes
UN Number: Not regulated under most international guidelines (check local regulations)
Proper Shipping Name: Tripropylene Glycol n-Butyl Ether
Transport Hazard Class: Not applicable
Packing Group: Not applicable
Environmental Hazards: Not marine pollutant under IMDG
Transport Precautions: Secure containers to prevent leaks, avoid exposure to high heat or rough handling during transit
OSHA Status: Not specifically regulated as hazardous, general chemical safety applies
TSCA Inventory: Listed
SARA Title III: Not subject to section 313
State Regulations: Check for specific state reporting or labeling requirements; some may require workplace notices
Canada DSL/NDSL: Listed
EU Regulations: REACH registered, follow workplace exposure limits and safety measures
Other: Employers must provide training and hazard communication for all users
