Product Name: Dibutyl Adipate and Diisobutyl Adipate Mixture
Chemical Family: Aliphatic esters
Recommended Use: Plasticizer, lubricant, solvent
Manufacturer: Information available by request
Emergency Contact: Refer to local emergency services or poison control center
Synonyms: DBA, DIBA Blend
CAS Numbers: Dibutyl Adipate: 105-99-7, Diisobutyl Adipate: 6938-94-9
UN Number: Not regulated as hazardous for transport under most conditions
Classification: Not classified as hazardous under GHS or OSHA standards, but not considered safe for ingestion or prolonged skin contact
Signal Word: None required
Hazard Statements: Slight skin irritation possible, light eye irritant, ingestion may cause digestive upset
Precautionary Statements: Avoid contact with eyes and skin, avoid inhalation of vapors and mist, use adequate ventilation
Pictograms: No pictogram required by GHS
Other Hazards: May cause minor environmental impact if released in large quantities; slippery when spilled
Ingredient 1: Dibutyl Adipate
Chemical Formula: C14H26O4
Concentration: 40–60% by weight
CAS Number: 105-99-7
Ingredient 2: Diisobutyl Adipate
Chemical Formula: C16H30O4
Concentration: 40–60% by weight
CAS Number: 6938-94-9
Impurities/Stabilizers: None relevant
General Advice: Remove contaminated clothing, seek fresh air and medical attention if symptoms persist
Eye Contact: Rinse eyes gently with plenty of water for at least 15 minutes; remove contacts if present, continue rinsing
Skin Contact: Wash with soap and water, rinse thoroughly, seek medical attention if irritation persists
Inhalation: Move to fresh air, ensure airway is clear, seek medical advice if symptoms develop or persist
Ingestion: Rinse mouth, do not induce vomiting except on medical advice, seek medical attention
Most Important Symptoms: Redness, discomfort, coughing, gastrointestinal upset
Notes to Physician: Symptomatic treatment, no specific antidote
Suitable Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical powder, or carbon dioxide
Unsuitable Extinguishing Media: Direct water jet may spread product
Specific Hazards: May produce carbon oxides under fire conditions, irritating fumes possible
Protective Equipment: Firefighters require self-contained breathing apparatus, full protective gear
Special Procedures: Cool exposed containers with water spray, avoid runoff to drains or water courses
Explosion Data: Not explosive, does not form flammable vapors at ambient temperature
Personal Precautions: Wear gloves, eye protection, suitable clothing, avoid vapors
Environmental Precautions: Prevent entry into sewers, water courses, soil; contain spill to limit environmental impact
Small Spills: Absorb with inert material such as sand, collect in suitable containers
Large Spills: Dike and contain spill, collect with non-sparking tools, ventilate area
Cleanup Methods: Wash remaining residue with water and detergent, dispose according to local guidelines
Reporting: Notify authorities if spill affects public waterways or environment
Handling Precautions: Avoid contact with eyes, skin; do not breathe vapors; use in well-ventilated areas
Storage Conditions: Store in tightly closed containers, keep in a cool, dry, well-ventilated place, away from incompatible materials such as strong oxidizers
Suitable Materials: Stainless steel, polyethylene, glass
Unsuitable Materials: Copper, aluminum, rubber composites
Safe Handling Advice: Clean spills immediately to prevent slip hazards, avoid static electricity buildup
Other Precautions: Keep away from food and drink, use only as intended
Occupational Exposure Limits: No established limits under OSHA, ACGIH, or NIOSH for these components
Engineering Controls: Local exhaust ventilation or general ventilation to maintain air concentrations below exposure guidelines
Personal Protective Equipment:
• Eye Protection: Safety goggles or face shield
• Hand Protection: Chemical-resistant gloves
• Skin Protection: Long sleeves, closed footwear
• Respiratory Protection: Use NIOSH-approved respirator when vapor/mist is generated, especially if ventilation is insufficient
Hygiene Measures: Wash hands after handling, remove contaminated clothing before eating, drinking, or smoking
Appearance: Clear, colorless to pale yellow liquid
Odor: Slight, ester-like odor
Odor Threshold: Not established
pH: Neutral
Melting Point: -30°C to -48°C (depending on ratio)
Boiling Point: 340°C–360°C at 760 mmHg
Flash Point: 187°C–200°C (closed cup)
Evaporation Rate: Very slow
Flammability: Not classified as flammable
Upper/Lower Explosion Limits: Not applicable
Vapor Pressure: <0.01 mmHg at 20°C
Vapor Density: Heavier than air
Relative Density: 0.98–0.99 (water = 1)
Solubility: Insoluble, but may form emulsions in water
Partition Coefficient n-octanol/water: log Pow >4
Auto-ignition Temperature: >390°C
Decomposition Temperature: Not determined
Viscosity: 7–15 cSt at 25°C
Chemical Stability: Stable under recommended storage and handling conditions
Possibility of Hazardous Reactions: Non-reactive under normal use, reacts with strong oxidizing agents
Conditions to Avoid: Excessive heat, open flames, incompatible materials
Incompatible Materials: Strong acids, bases, oxidizing agents
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, irritating fumes under combustion
Polymerization: Will not occur
Acute Toxicity: Dibutyl Adipate LD50 oral (rat) > 30,000 mg/kg; Diisobutyl Adipate expected similar
Skin Corrosion/Irritation: Mild, not classified as corrosive
Serious Eye Damage/Irritation: Minor irritation possible
Respiratory Sensitization: Not classified as a sensitizer
Skin Sensitization: Not classified as a sensitizer
Carcinogenicity: No evidence from animal studies, not listed by IARC, NTP, or OSHA
Mutagenicity: No data to suggest mutagenic potential
Reproductive Toxicity: No evidence from available animal studies
STOT (Specific Target Organ Toxicity): Not classified
Repeated Dose Toxicity: No significant systemic effects at low exposure levels
Symptoms: Skin redness, mild eye discomfort, nausea, abdominal discomfort on ingestion
Ecotoxicity: Low acute aquatic toxicity (LC50, EC50 > 100 mg/L for fish, daphnia, algae)
Persistence and Degradability: Readily biodegradable in aquatic and soil environments
Bioaccumulation Potential: Low (estimated BCF <100)
Mobility in Soil: Moderate, can adsorb to sediments and degrade
Other Adverse Effects: Large spills may impact aquatic life by forming surface films limiting oxygen transfer
Additional Information: Not expected to cause significant environmental harm at recommended uses
Waste Treatment Methods: Dispose in accordance with local, regional, and national regulations
Recommended Disposal: Incineration in an approved facility; treat as industrial waste
Container Disposal: Rinse containers, offer for recycling or reconditioning if possible
Special Precautions: Avoid release to natural waters and sewers
Waste Code: Not classified as hazardous waste under RCRA
Additional Considerations: Always check local and state requirements for proper disposal
UN Number: Not regulated for ground, air, or sea
Proper Shipping Name: Non-hazardous chemical mixture
Transport Hazard Class: Not applicable
Packing Group: Not applicable
Environmental Hazards: Not classified as marine pollutant
Special Precautions for User: Use spill-proof packaging, avoid loading with incompatible substances
Additional Transport Information: Follow general chemical hygiene practices for bulk movement
OSHA Status: Not hazardous
TSCA Inventory: Components listed
SARA Title III: Not regulated under Sections 302, 304, 313
California Proposition 65: No listing
Canada (DSL/NDSL): All ingredients listed or exempt
REACH Registration: Registered in the EU for permitted uses
Other Regulatory Data: Conforms to RoHS and REACH limits for hazardous content
Workplace Classification: Not controlled, basic hygiene recommended
