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Material Safety Data Sheet (MSDS) for Ethylene Glycol Hexyl Ether

1. Identification

Product Name: Ethylene Glycol Hexyl Ether
Synonyms: 2-(2-Ethoxyethoxy)ethanol, Hexyloxyethanol
CAS Number: 112-25-4
Manufacturer: [Insert Manufacturer Name Here]
Recommended Uses: Solvent for cleaning, paints, coatings, adhesives, ink removers, degreasing
Emergency Contact: [Insert Emergency Contact Number]

2. Hazard Identification

Classification: Flammable liquid, Harmful if swallowed, Causes skin and eye irritation, May cause respiratory irritation
Label Elements: Signal word: Warning, Hazard statements: H302 – Harmful if swallowed, H315 – Causes skin irritation, H319 – Causes serious eye irritation
Pictograms: Exclamation mark, Flame
Hazard Symbols: Xn (Harmful), Xi (Irritant)
Precautionary Statements: Wear protective gloves and eye/face protection, Avoid inhalation of vapors, Wash hands well after use, Keep container tightly closed in a cool, well-ventilated spot

3. Composition / Information on Ingredients

Chemical Name: Ethylene Glycol Hexyl Ether
Chemical Formula: C8H18O2
CAS Number: 112-25-4
Concentration: ≥ 99% by weight
Impurities: Trace amounts of related glycol ethers
Additives: n/a

4. First Aid Measures

Inhalation: Move to fresh air, get medical attention if symptoms persist (cough, dizziness, nausea)
Skin Contact: Remove contaminated clothing, rinse skin under running water for 10-20 minutes, seek medical attention for persistent irritation
Eye Contact: Rinse eyes gently with water for at least 15 minutes, remove contact lenses, continue rinsing and get medical advice
Ingestion: Do not induce vomiting, rinse mouth with water, seek immediate medical attention, provide information about the product for treatment guidance

5. Fire-Fighting Measures

Suitable Extinguishing Media: Foam, dry chemical powder, carbon dioxide, water spray (do not use water jet directly)
Unsuitable Media: Water jet can spread the chemical
Special Hazards: Vapors are heavier than air, may travel and ignite at distant sources, combustion creates toxic fumes (carbon monoxide, carbon dioxide)
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective clothing
Firefighting Instructions: Cool exposed containers with water spray, avoid inhalation of fumes, contain run-off from firefighting to prevent environmental contamination

6. Accidental Release Measures

Personal Precautions: Remove ignition sources, ensure ventilation, use personal protective equipment like gloves and goggles
Environmental Precautions: Prevent the chemical from entering drains, surface water, or soil
Containment: Absorb with inert material like sand or earth, store in a covered and labeled disposable container
Clean-up Procedures: Clean the surface with detergent and water after bulk removal, dispose of all clean-up materials safely

7. Handling and Storage

Handling: Work in well-ventilated areas, avoid inhalation and skin contact, use explosion-proof devices, keep containers closed when not in use
Storage: Keep above freezing and below 30°C, store in tightly closed original containers, place in a cool, dry area away from direct sunlight, oxidizing agents, acids, and ignition sources
Incompatible Materials: Strong oxidizers, acids, alkalis, sources of ignition
Hygiene Practices: Wash hands before breaks and after handling, do not eat or drink around the product

8. Exposure Controls and Personal Protection

Exposure Limits: OSHA or ACGIH has not established specific limits for this substance; recommend using general glycol ether standards
Engineering Controls: Use local exhaust ventilation to minimize vapor exposure, provide eye-wash stations
Personal Protective Equipment: Chemical-resistant gloves (nitrile, neoprene), splash-proof goggles, long-sleeve clothing, use a respirator (organic vapor cartridge) for high vapor scenarios
Workplace Practices: Remove contaminated clothing right away, keep safety shower within reach, do not smoke near work areas

9. Physical and Chemical Properties

Appearance: Colorless liquid
Odor: Mild, ether-like
pH: Neutral (estimation)
Melting Point: -70°C
Boiling Point: 210°C
Flash Point: 96°C (Closed cup)
Autoignition Temperature: 240°C
Vapor Pressure: 0.3 mmHg at 20°C
Solubility: Miscible with water, organic solvents
Density: 0.87 g/cm3 at 20°C
Viscosity: ~6 mPa·s at 20°C
Partition Coefficient (log Pow): 0.58

10. Stability and Reactivity

Chemical Stability: Stable under recommended conditions, does not polymerize spontaneously
Possibility of Hazardous Reactions: Contact with strong oxidizers and acids produces toxic gases, high temperatures can cause decomposition
Conditions to Avoid: Open flames, sparks, high heat, incompatible chemicals
Decomposition Products: Carbon monoxide, carbon dioxide, aldehydes occur with thermal breakdown
Incompatibility: Strong acids, strong bases, oxidizing agents

11. Toxicological Information

Acute Toxicity: Oral LD50 (rat) 1,917 mg/kg, Dermal LD50 (rabbit) >2,000 mg/kg
Skin Irritation: May cause redness, dryness, cracking
Eye Irritation: Can cause significant discomfort or injury on prolonged exposure
Inhalation: Short exposures cause irritation of nose and throat, dizziness can follow high vapor levels
Chronic Exposure: Repeated long-term contact may damage liver and kidneys, reproductive effects appear unlikely but data limited
Sensitization: No confirmed evidence of allergy development
Carcinogenicity: Not classified by IARC or NTP as a human carcinogen

12. Ecological Information

Ecotoxicity: Harmful to aquatic organisms at high concentrations (EC50 for algae: 672 mg/L, Daphnia: 661 mg/L)
Persistence and Degradability: Readily biodegradable, breakdown through microbial action within weeks
Bioaccumulation: Very low potential (log Pow below 1)
Mobility: Highly mobile in soil and water due to good solubility
Other Environmental Effects: Spills can damage aquatic habitats by reducing oxygen availability

13. Disposal Considerations

Waste Disposal: Collect in sealed containers, send for incineration or chemical treatment at approved facilities
Unused Product: Handled as hazardous waste, never pour down drains or natural water sources
Contaminated Packaging: Dispose through specialized waste contractors, rinse thoroughly before recycling or disposal
Regulations: Comply with local, regional and national hazardous waste guidelines for storage, transportation, and record-keeping

14. Transport Information

UN Number: UN 1993 (if shipped as a flammable liquid mixture), not regulated for transport in pure form under most codes
Proper Shipping Name: Flammable liquid, n.o.s. (contains Ethylene Glycol Hexyl Ether)
Transport Hazard Class: 3 (Flammable liquids)
Packing Group: III
Environmental Hazards: Not a marine pollutant
Special Precautions: Keep tightly sealed, segregate from food or feed cargo, follow labeling and documentation rules strictly

15. Regulatory Information

Regulatory Status: Listed on TSCA inventory (US), REACH registered (EU), DSL (Canada)
Hazard Categories: Immediate (acute) health hazard, Fire hazard under OSHA Hazard Communication Standard
Labeling Requirements: Must carry warning and hazard pictograms, safety data made available for workers
Restrictions: Avoid use in products for direct skin application without additional safety review
Reporting Obligations: Meet national and regional requirements for reporting hazardous substance usage and spill incidents