Product Name: Ethylene Glycol Ethyl Ether Acetate
Synonyms: 2-Ethoxyethyl acetate, EGEEA, Glycol ether acetate
CAS Number: 111-15-9
Recommended Use: Solvent in paints, coatings, inks, and cleaners
Supplier: Listed chemical distributor or manufacturer, check with company for specific contact details
Emergency Telephone: Chemtrec or local emergency number associated with manufacturer/distributor
GHS Classification: Flammable Liquid (Category 3), Acute Toxicity-Oral (Category 4), Skin Irritant (Category 3), Eye Irritant (Category 2A), Reproductive Toxicity (Category 2)
Pictograms: Flame, Exclamation Mark, Health Hazard
Signal Word: Warning
Hazard Statements: Flammable liquid and vapor, harmful if swallowed, causes skin and eye irritation, suspected of damaging fertility or the unborn child
Precautionary Statements: Avoid breathing vapors, use only in well-ventilated places, keep container tightly closed, keep away from heat and open flames, wash hands thoroughly after handling, use protective gloves and eye protection
Chemical Name: Ethylene Glycol Ethyl Ether Acetate
Component: Ethylene Glycol Ethyl Ether Acetate
Concentration: >99%
CAS Number: 111-15-9
Impurities/Additives: Trace solvents or stabilizers, typically present in minimal amounts as byproducts of manufacturing, often below 0.1%
Inhalation: Move person to fresh air, keep airway clear, seek medical attention if symptoms develop such as coughing or dizziness
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and plenty of water, see a doctor for persistent irritation or allergic reaction
Eye Contact: Rinse with large volumes of water for a minimum of 15 minutes, remove contact lenses if present and easy to do, consult an eye specialist if any pain or vision problems continue
Ingestion: Rinse mouth with water, do not induce vomiting, seek medical advice immediately, show label or MSDS if available at the clinic
Most Important Symptoms: Eye redness, skin dryness or cracking, headache, nausea, drowsiness, possible effects on kidney or central nervous system with long-term exposure
Suitable Extinguishing Media: Water spray, carbon dioxide, foam, dry chemical powder
Unsuitable Extinguishing Media: Direct water jet can spread fire
Special Hazards: Produces irritating, potentially toxic gases when burning (carbon monoxide, carbon dioxide, acetic acid vapor)
Protective Equipment for Firefighters: Self-contained breathing apparatus, full protective gear for chemical fires
Additional Advice: Remove containers from fire zone if safe, cool exposed containers with water spray to prevent pressure build-up and explosion
Personal Precautions: Remove all ignition sources, ventilate area, avoid breathing vapors or contact with skin and eyes, wear protective gloves and goggles
Environmental Precautions: Prevent leakage to drains, sewers, or bodies of water, contain spill with inert absorbent (sand or inert clay); avoid soil contamination
Cleanup Methods: Soak up with non-combustible absorbent material (sand, earth, vermiculite), place in suitable closed waste container, dispose according to local regulations, wash spill area with water to remove residues
Notification: Inform local environmental authorities if large quantities are released into environment
Handling: Use only in well-ventilated areas, avoid breathing vapors or direct contact with liquid, wear personal protective equipment, keep away from heat, sparks, and open flames, do not eat, drink, or smoke while handling chemicals
Storage: Store in tightly sealed original containers, in cool, dry, and well-ventilated places, segregate from incompatible substances (strong acids, alkalis, oxidizing agents), protect from direct sunlight and sources of ignition, keep containers upright, label all storage areas clearly
Additional Information: Keep containers closed when not in use, store away from food and drinks
Occupational Exposure Limits: OSHA PEL 100 ppm (TWA), ACGIH TLV 50 ppm (TWA), check national guidelines for country-specific exposure limits
Engineering Controls: Use local exhaust ventilation, handle only in fume hood if possible, install explosion-proof ventilation systems in work area
Personal Protective Equipment: Chemical-resistant gloves (nitrile or neoprene), protective clothing (lab coat, coveralls), safety goggles or face shield, NIOSH-approved respirator for insufficient ventilation or high vapor concentration
Hygiene Measures: Wash hands before breaks, after finishing work; remove contaminated clothing and equipment before leaving work area
Appearance: Clear, colorless to slightly yellow liquid
Odor: Mild, pleasant ether-like odor
Odor Threshold: Not established precisely; detectable at low ppm
pH: Not applicable for organic liquid
Melting Point: -70°C
Boiling Point: 156°C
Flash Point: 49°C (Closed Cup)
Evaporation Rate: 0.23 (butyl acetate=1)
Flammability: Flammable liquid
Vapor Pressure: 1.1 mm Hg @ 20°C
Vapor Density: 4.8 (air = 1)
Relative Density: 0.97 g/cm³ @ 20°C
Solubility: Miscible with water and many organic solvents
Partition Coefficient (n-octanol/water): 0.18
Autoignition Temperature: 400°C
Decomposition Temperature: Not available
Viscosity: 1.3 mPa.s @ 20°C
Chemical Stability: Remains stable under normal storage and use conditions, avoid temperatures above boiling point and prolonged exposure to heat
Reactivity: May react with strong oxidizing agents such as perchlorates, nitrates, permanganates
Hazardous Reactions: Generates hazardous gases when exposed to strong acids or bases, forms explosive mixtures with air at vapor concentrations
Decomposition Products: Carbon monoxide, carbon dioxide, acetic acid
Storage Incompatibility: Incompatible with strong acids, alkalis, oxidizers, and some plastics or rubbers
Acute Toxicity: LD50 Oral (rat): 1780 mg/kg; LD50 Dermal (rabbit): >5000 mg/kg
Skin Corrosion/Irritation: Causes mild to moderate irritation on prolonged skin contact, absorbed through skin in high concentrations
Eye Damage/Irritation: Causes moderate irritation, redness, tearing
Respiratory Sensitization: May cause coughing, sore throat, dizziness at high vapor concentrations
Germ Cell Mutagenicity: No reliable data indicating mutagenic effects
Carcinogenicity: Not classified as carcinogen by IARC, NTP, or OSHA
Reproductive Toxicity: Evidence from studies on similar glycol ethers suggests risks to fetal development and fertility with long-term exposure
STOT - Single Exposure: Possible drowsiness, headache
STOT - Repeated Exposure: Risks to kidneys and central nervous system over long periods
Ecotoxicity: Toxic to aquatic organisms at high concentrations, LC50 (fish, 96hr): 600 mg/L, EC50 (Daphnia magna, 48hr): 600-1200 mg/L
Persistence and Degradability: Readily biodegradable, does not accumulate in the environment over time
Bioaccumulative Potential: Low, log Kow 0.18 means substance moves quickly between water and organisms
Mobility in Soil: Moves easily in soil due to high solubility, potential groundwater contaminant after large spill
Other Adverse Effects: No significant ozone depletion, photochemical ozone creation possible if released as vapor
Waste Treatment Methods: Incinerate chemical waste at approved facility, avoid open burning or pouring down drain
Container Disposal: Triple rinse with water or suitable solvent, puncture and dispose through authorized hazardous waste handler
Local Requirements: Follow federal and local hazardous waste regulations strictly, do not reuse uncleaned containers for food or beverages
Additional Advice: Do not mix with general waste, inform authorities if large quantities are disposed in landfills or sewers
UN Number: 1993
Proper Shipping Name: Flammable Liquid, N.O.S. (Ethylene Glycol Ethyl Ether Acetate)
Transport Hazard Class: 3 (Flammable Liquid)
Packing Group: III
Label: Flammable Liquid
Marine Pollutant: No
Special Precautions: Follow vehicle and container safety requirements, keep away from direct sunlight and heat, secure packaging well to avoid leaks during transport
OSHA: Regulated as hazardous chemical, subject to workplace safety and health standards
SARA Title III: Product subject to community right-to-know reporting, listed on Section 313
TSCA: Component appears on the TSCA inventory
REACH (EU): Included in REACH registration; additional restrictions for reproductive toxicity apply across Europe
WHMIS (Canada): B2 (Flammable Liquids), D2A (Very Toxic), D2B (Toxic)
Other Regulations: Listed on major national inventories (such as DSL, EINECS, AICS), further details from manufacturer and local regulatory authority
