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Material Safety Data Sheet: Diisobutyl Adipate

Identification

Product Name: Diisobutyl Adipate
Chemical Formula: C14H26O4
CAS Number: 141-04-8
Synonyms: DIBA, Adipic Acid Diisobutyl Ester
Recommended Use: Plasticizer, solvent for resins, ingredient in cosmetic products
Manufacturer Contact: Contact provided on the shipping label for safety updates and detailed product inquiries
Emergency Telephone: Provided in case of exposure, ingestion, or large-scale spill
Address: Manufacturer or supplier address as printed on label for shipping, recalls, or compliance verification

Hazard Identification

GHS Classification: Not classified as hazardous under current regulation
Hazard Statement: Prolonged or repeated exposure may cause mild irritation to the eyes and skin; ingestion in large amounts may lead to abdominal discomfort
Label Elements: No specific pictogram required under standard global harmonized system
Precautionary Statements: Avoid prolonged or repeated contact; practice good hygiene.
Symptoms of Exposure: Redness, itching, mild headache, stomach ache upon significant exposure
Chronic Effects: No confirmed long-term health risks in occupational settings reported at regulated exposure levels

Composition / Information on Ingredients

Chemical Name: Diisobutyl Adipate
Concentration: ≥ 99%
Impurities: Adipic acid trace, isobutanol <0.1%
Molecular Weight: 258.36 g/mol
Other Components: None identified as hazardous
Mixture Status: Single chemical substance, not a mixture

First Aid Measures

Inhalation: Move person to fresh air; seek medical guidance if symptoms such as coughing or shortness of breath occur
Skin Contact: Wash skin thoroughly with soap and water; remove contaminated clothing; seek help if irritation persists
Eye Contact: Rinse carefully with water for 15 minutes; remove contact lenses if present; contact a physician if discomfort continues
Ingestion: Do not induce vomiting; rinse mouth, drink water; seek prompt medical attention
Most Important Symptoms: Minor, reversible skin or eye irritation; no severe symptoms noted at common occupational exposures
Note to Doctor: Treat symptomatically; monitor severe exposures for gastric upset or signs of allergic reaction

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, foam, carbon dioxide, or water spray
Unsuitable Extinguishing Media: Direct water jet, which may cause splattering or spread
Special Hazards: May produce irritating smoke and fumes if involved in fire; decomposition products include carbon oxides
Protective Equipment for Firefighters: Wear full protective gear and self-contained breathing apparatus
Specific Techniques: Keep containers cool by spraying with water; block runoff to drains or waterways to contain contamination
Flash Point: Approx. 190°C (374°F)
Explosion Limits: Not easily explosive under normal conditions

Accidental Release Measures

Personal Precautions: Use personal protective equipment; avoid contact with skin, eyes, and clothing
Environmental Precautions: Prevent entry into sewers, waterways, or soil; block off spill area to minimize environmental damage
Methods for Cleaning Up: Contain spill with absorbent material (sand, earth, inert absorbent); place in labeled waste containers
Decontamination: Wash spill area with detergent and water; ventilate enclosed spaces well after cleanup
Disposal: Follow waste handling protocols as specified by local regulations
Small Spills: Wipe up with absorbent rags and dispose of responsibly
Large Spills: Evacuate waste as chemical hazardous waste; call spill response team if above release threshold

Handling and Storage

Handling Precautions: Wear suitable gloves and eye protection; use only with adequate ventilation; avoid inhalation of vapors
Safe Work Practices: Do not eat, drink, or smoke during use; practice routine handwashing before breaks
Storage Conditions: Keep container tightly closed in a cool, dry, well-ventilated place
Compatibility: Store away from oxidizing materials and strong acids
Transfer Instructions: Use pumps or dispensers designed for chemical liquid transfer to minimize spills and splashes
Storage Life: Stable under recommended storage conditions, store away from direct sunlight and high heat for best shelf life

Exposure Controls and Personal Protection

Control Parameters: No occupational exposure limits established for diisobutyl adipate
Engineering Controls: Use adequate local exhaust or general ventilation to control exposure below threshold limit values
Personal Protective Equipment: Protective gloves (nitrile or chemical-resistant), safety glasses or goggles, suitable protective clothing
Respiratory Protection: Use a certified organic vapor respirator if ventilation is insufficient
Hygiene Measures: Wash hands, forearms, and face thoroughly after handling; remove contaminated clothing immediately
Environmental Exposure Controls: Prevent release into storm drains, soil, or open water

Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Mild ester odor
Boiling Point: 329°C
Melting Point: -45°C
Flash Point: 190°C (374°F) (Closed cup method)
Solubility: Insoluble in water, miscible with most organic solvents
Vapor Pressure: <0.01 mmHg at 20°C
Specific Gravity: 0.96 (Water = 1)
Viscosity: About 11 mPa·s at 20°C
pH: Not applicable
Partition Coefficient (log Kow): Approx. 4.2
Evaporation Rate: Much slower than butyl acetate

Stability and Reactivity

Chemical Stability: Stable under recommended handling and storage conditions
Conditions to Avoid: Prolonged heat, direct sunlight, sources of ignition
Incompatible Materials: Strong oxidizing agents, acids, alkalis
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, small amounts of irritant aldehydes if overheated
Polymerization: No hazardous polymerization reported
Reactivity: No vigorous reactions with common materials under normal use

Toxicological Information

Acute Toxicity – Oral: LD50 (Rat) > 5000 mg/kg (low acute toxicity)
Acute Toxicity – Dermal: LD50 (Rat) > 5000 mg/kg
Inhalation Toxicity: No significant effects reported at vapor concentrations generated at room temperature
Skin Corrosion/Irritation: May cause mild, reversible irritation on prolonged contact
Eye Damage/Irritation: Eye irritation possible; not classified as corrosive
Respiratory Sensitization: No data indicating respiratory sensitization
Carcinogenicity: Not listed by IARC, NTP, OSHA as a carcinogen
Reproductive Toxicity: No known or expected effects on reproduction at standard exposure
Chronic Effects: No cumulative long-term effects reported at controlled use levels
Other Effects: No established links to organ toxicity, mutagenicity, or teratogenicity at industrial exposure limits

Ecological Information

Aquatic Toxicity: Low toxicity expected in aquatic systems; LC50 (96h, fish) > 100 mg/L
Persistence and Degradability: Readily biodegradable in standard tests; does not persist in the environment
Bioaccumulation Potential: Moderate potential, log Kow > 4
Soil Mobility: Low, due to poor water solubility; likely to partition to sediment and soil
Ecotoxicity Summary: No evidence of significant bioaccumulation risk or chronic aquatic effects at environmental concentrations seen with normal use
Regulatory Status: Not listed as hazardous to aquatic environment by key international conventions

Disposal Considerations

Waste Treatment Methods: Dispose of product as hazardous chemical waste in accordance with relevant local, regional, and national regulations
Packaging Cleaning: Empty containers should be drained completely, rinsed with water, and offered for recycling or disposal
Contaminated Packaging: Treat as hazardous and dispose with approved waste processors
Incineration: Permitted in facilities equipped to handle organic esters and recover energy
Other Disposal Recommendations: Do not discharge into drains, sewers, or waterways; collect and ship using licensed hazardous-waste companies

Transport Information

UN Number: Not classified as dangerous goods for transportation
Transport Hazard Class:** Not regulated
Packing Group: Not applicable
Marine Pollutant:** Not considered marine pollutant
Special Precautions for Transport:** Store away from food or feed; ensure containers are secured and labeled
DOT (US): Not regulated
ICAO/IATA: Not regulated
IMDG Code: Not regulated by International Maritime Dangerous Goods Code

Regulatory Information

TSCA: Listed on the US Toxic Substances Control Act inventory
REACH (EU): Registered and permitted for intended use in Europe
OSHA: Not listed as a hazardous chemical under Hazard Communication Standard (29 CFR 1910.1200)
WHMIS (Canada): Not classified as hazardous under Canadian WHMIS legislation
Inventory Listings: Listed in AICS, DSL, ENCS, and PICCS for compliance with worldwide shipping and import regulation
Label Requirements: No specific hazard labeling mandated; standard chemical labeling recommended for worker safety
Other National Regulations: Consult local authorities for further restrictions or requirements on storage, use, and transportation