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Material Safety Data Sheet (MSDS) – Dibutyl Adipate

Identification

Product Name: Dibutyl Adipate
Chemical Formula: C14H26O4
Synonyms: Adipic acid dibutyl ester, DBE, Di-n-butyl adipate
CAS Number: 105-99-7
Recommended Use: Plasticizer in plastics, solvent in cosmetics, component in lubricants and adhesives
Manufacturer Information: Manufacturer address, emergency phone number, and supplier contact details should be included on packaging and company documentation for verification purposes.

Hazard Identification

Classification: Not classified as hazardous under most global regulations, but can cause skin and eye irritation on direct contact
Signal Word: None
Hazard Statements: May cause mild skin irritation, prolonged or repeated exposure can dry skin, harmful if ingested in large amounts but low acute toxicity, vapors or mists may be irritating to respiratory system
Precautionary Statements: Avoid contact with eyes and skin, do not ingest, use with proper ventilation, wash hands thoroughly after handling
GHS Label Elements: No symbol required under GHS criteria for this substance

Composition / Information on Ingredients

Chemical Name: Dibutyl Adipate
Concentration: 98%–100%
CAS Registry Number: 105-99-7
Impurities: Contains minor contaminants from manufacture below reporting thresholds, not expected to significantly contribute to health risk based on current manufacturing standards.

First Aid Measures

Inhalation: Move to fresh air, keep victim warm and at rest, seek medical attention if symptoms persist (such as coughing, throat irritation, or dizziness)
Eye Contact: Rinse immediately with plenty of water, lifting eyelid occasionally, remove contact lenses if present and easy to do, continue rinsing for at least 15 minutes, seek medical advice if irritation remains
Skin Contact: Remove contaminated clothing, wash skin thoroughly with soap and water, seek medical advice if rash or irritation develops
Ingestion: Do not induce vomiting, rinse mouth, offer water to drink, get immediate medical attention if feeling unwell or for large accidental ingestion
Most Important Symptoms: Redness, irritation, dryness of skin, irritation of eyes and throat

Fire-Fighting Measures

Suitable Extinguishing Media: Use foam, dry chemical, or carbon dioxide for small fires, water spray or fog for large fires, avoid direct water jets since product may float
Specific Hazards: Product can release toxic fumes such as carbon monoxide and carbon dioxide in a fire, combustion generates acrid smoke
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective clothing to prevent contact with skin and eyes
Special Procedures: Prevent runoff from fire control or dilution from entering waterways; if deemed safe, remove containers from fire area to minimize risk.

Accidental Release Measures

Personal Protection: Use appropriate protective equipment, avoid breathing vapors or mist, provide sufficient ventilation
Environmental Precautions: Prevent further leakage or spillage if safe to do so, do not allow product to reach drains or surface water
Containment: Absorb with inert material such as sand, earth, or vermiculite, transfer to suitable containers for disposal
Cleanup Methods: Clean contaminated area with detergent, avoid direct contact, use nonsparking tools
Disposal: Dispose of in accordance with local/national regulations as described in disposal section.

Handling and Storage

Safe Handling: Handle using safe hygiene practices, avoid direct contact with eyes and skin, avoid inhalation of mist or spray, do not eat or drink in work area
Storage Conditions: Store in cool, dry, well-ventilated area, protect from heat and incompatible materials, keep container tightly closed
Incompatibilities: Keep away from strong oxidizing agents and acids which can cause hazardous reactions
Other Precautions: Store in original containers labeled in compliance with applicable laws, keep away from foodstuffs and sources of ignition.

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established exposure limits for dibutyl adipate
Engineering Controls: Use local exhaust or general ventilation to maintain airborne levels below recommended exposure limits, if generated
Respiratory Protection: Not required under normal circumstances, use approved respirator if vapor or mist may occur
Eye Protection: Safety goggles or chemical splash glasses recommended
Skin Protection: Wear chemical-resistant gloves, long-sleeved clothing as best practice
Hygiene Measures: Wash hands before eating, smoking, or using the restroom, remove and clean contaminated clothing before reuse

Physical and Chemical Properties

Appearance: Clear, colorless to pale yellow liquid
Odor: Mild, characteristic
Odor Threshold: Not established
pH: Not applicable
Melting Point/Freezing Point: -37°C
Boiling Point/Range: 340°C
Flash Point: 174°C (closed cup)
Evaporation Rate: Not readily available
Flammability: Combustible liquid
Vapor Pressure: < 0.01 mmHg at 20°C
Vapor Density: Approximately 8 (air = 1)
Density: 0.97 g/cm³ at 20°C
Solubility in Water: Slightly soluble (about 27 mg/L at 25°C)
Partition Coefficient n-octanol/water (log Kow): 4.8
Auto-ignition Temperature: ~410°C
Decomposition Temperature: Not determined
Viscosity: 8.4 mPa·s at 20°C

Stability and Reactivity

Chemical Stability: Stable under recommended storage and handling conditions
Reactivity: Not reactive under normal conditions
Hazardous Polymerization: Will not occur
Incompatible Materials: Strong oxidizers and acids
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, possibly other toxic compounds during combustion or extreme heating

Toxicological Information

Routes of Exposure: Inhalation, skin and eye contact, ingestion
Acute Toxicity: Low, oral LD50 in rats > 7,400 mg/kg (relatively non-toxic by ingestion)
Skin Corrosion/Irritation: May cause mild irritation with prolonged or repeated contact
Eye Damage/Irritation: May cause mild eye irritation
Respiratory Sensitization: Not expected to be a respiratory sensitizer
Carcinogenicity: Not listed by IARC, NTP, OSHA as a carcinogen
Other Effects: No evidence of mutagenic, teratogenic, or reproductive effects in available studies
Chronic Exposure: Prolonged skin contact may lead to drying or redness; high vapor concentrations are unlikely under normal use

Ecological Information

Aquatic Toxicity: Practically non-toxic to aquatic organisms with LC50 (Fish, 96h) > 1,000 mg/L
Biodegradability: Readily biodegradable under aerobic conditions
Bioaccumulation Potential: Low to moderate based on log Kow, but rapid biodegradation limits long-term accumulation
Persistence: Expected to degrade in soil and water environments
Mobility in Soil: Low mobility due to low water solubility and strong adsorption to soil particles
Other Environmental Information: No known significant environmental hazards under recommended use, avoid uncontrolled release to waterways

Disposal Considerations

Waste Disposal Methods: Dispose of contents/container in accordance with local/regional/national regulations, do not discharge into drains or surface waters
Contaminated Packaging: Empty containers may contain residue, handle as hazardous waste, triple rinse before disposal or recycling
Special Disposal Notes: Incineration or disposal in approved landfill in accordance with statutory requirements
Considerations for Users: Always follow local waste management standards, never reuse container for food or drinking water

Transport Information

UN Number: Not regulated under most international and regional transport regulations
Proper Shipping Name: Dibutyl Adipate
Hazard Class: Not classified
Packing Group: Not classified
Environmental Hazards: Not considered a marine pollutant
Transport Precautions: Protect from physical damage and extreme temperatures during transport, keep containers secure and labeled, avoid transport with incompatible materials

Regulatory Information

OSHA Status: Not hazardous under OSHA Hazard Communication Standard (29 CFR 1910.1200)
TSCA Inventory: Listed
REACH Registration: Registered in accordance with REACH (EC 1907/2006)
Canada (DSL/NDSL): Listed
SARA Title III (Sections 302/311/312/313): Not subject to reporting requirements
Other International Inventories: Included on major chemical inventories such as EINECS and AICS
Labeling Requirements: Label containers with recommended use, hazard statements, and emergency information
Other Regulations: Adhere to any regional, national, or international regulations applicable in location of use or distribution